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overpotential
[ oh-ver-puh-ten-shuhl ]
Word History and Origins
Origin of overpotential1
Example Sentences
Upon carrying out electrocatalytic water splitting, the team observed that Ni-W5N4 alloy catalyzed the hydrogen evolution reaction, resulting in 10 mA/cm2 current density at a small overpotential of 11 mV.
It showed a remarkable current density of 100 mA/cm2 at an overpotential of just 230 mV.
In forward bias, it exhibited a current density of 11 mA/cm2 at 181 mV overpotential.
A challenge for catalysis researchers is to combine the best of the biological and industrial approaches to nitrogen fixation — that is, to find a process that operates near ambient temperature and pressure, has minimal chemical overpotential, and does not require a capital-intensive plant to make ammonia on a large scale.
Forming N–H bonds with molybdenum nitrido complexes poses a considerable thermodynamic challenge, because N–H bonds are also weakened when bound to molybdenum, as noted by our group10; this effect is a source of chemical overpotential.
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