benzal chloride

noun

, Chemistry.

1. a colorless, oily liquid, C 7 H 6 Cl 2 , used chiefly in the synthesis of benzaldehyde, and in the manufacture of dyes.

Word History and Origins

Origin of benzal chloride¹

First recorded in 1875–80

Example Sentences

By heating benzal chloride with dry sodium acetate there is formed an acid known as cinnamic acid, a fragrant compound which derives its name from cinnamon, because the acid was prepared by the oxidation of oil of cinnamon by Dumas and Peligot in 1834.

From Project Gutenberg

The first of these is benzyl chloride, the second benzal chloride, and the third benzotrichloride or phenyl chloroform.

From Project Gutenberg

It was but a step from the laboratory into the factory in this case, and at the present time the aldehyde is made on a large scale by chlorinating boiling toluene beyond the stage of benzyl chloride, and heating the mixture of benzal chloride and benzotrichloride with lime and water under pressure.

From Project Gutenberg

This compound is readily oxidized to benzoic acid, C6H5�COOH, the aromatic residue being unattacked; nitric and sulphuric acids produce nitro-toluenes, C6H4�CH3�NO2, and toluene sulphonic acids, C6H4�CH3�SO3H; chlorination may result in the formation of derivatives substituted either in the aromatic nucleus or in the side chain; the former substitution occurs most readily, chlor-toluenes, C6H4�CH3�Cl, being formed, while the latter, which needs an elevation in temperature or other auxiliary, yields benzyl chloride, C6H5�CH2Cl, and benzal chloride, C6H5�CHCl2.

From Project Gutenberg