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diazonium salt
noun
- any of a group of salts of the general formula ArN 2 X, in which Ar represents an aryl group and X an anion, as benzenediazonium chloride, C 6 H 5 N(N)Cl, many of which are important intermediates in the manufacture of azo dyes.
diazonium salt
noun
- any of a class of compounds with the general formula ArN:N –M +, where Ar is an aryl group and M is a metal atom; made by the action of nitrous acid on aromatic amines and used in dyeing
Word History and Origins
Origin of diazonium salt1
Example Sentences
These iso-diazotates are formed much more readily when the aromatic nucleus in the diazonium salt contains negative radicals.
In this process the amine salt is dissolved in absolute alcohol and diazotized by the addition of amyl nitrite; a crystalline precipitate of the diazonium salt is formed on standing, or on the addition of a small quantity of ether.
Replacement of -NH2 by -OH:—The amine is diazotized and the aqueous solution of the diazonium salt is heated, nitrogen being eliminated and a phenol formed.
Oxyazo Compounds.—The oxyazo compounds are prepared by adding a solution of a diazonium salt to a cold slightly alkaline solution of a phenol.
Zincke found that the products obtained by coupling a diazonium salt with α-naphthol, and by condensing phenyl-hydrazine with α-naphthoquinone, were identical; whilst Meldola acetylated the azophenols, and split the acetyl products by reduction in acid solution, but obtained no satisfactory results.
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